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P-Hydroquinone, known as hydroquinone or hydroquinone in Chinese, is an important organic compound with the chemical formula C6H6O2 and a white crystalline form. This compound has a wide range of applications in the chemical industry, the pharmaceutical field, and the photographic industry. In terms of uses, P-Hydroquinone is mainly used in the production of black and white developers, anthraquinone dyes, azo dyes and so on. In the rubber industry, it is often used as an antioxidant, which helps to extend the service life of rubber products.
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According to the hygiene standard GB2760 (0.4007) for the use of food additives in the People's Republic of China, TBHQ can be used for edible oils, fried foods, dried fish products, biscuits, instant noodles, instant boiled rice, canned dried fruits, pickled meat products, roasted and fried nut foods (supplemented in February 2007), etc. The maximum usage is 0.2g/kg. It is generally recommended to use 0.01~0.02% of the total amount of oil.One dose is versatile and can effectively inhibit the growth of bacteria and molds.
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1.Product Characteristics1. Synthetic oil antioxidant TBHQ is a highly efficient, low-toxicity phenolic antioxidant with excellent antioxidant effect, and the antioxidant capacity is up to 5-7 times compared with existing food antioxidants such as BHA, BHT and PG.2. Synergistic: TBHQ can be used together with other antioxidants (such as BHA, B HT) and chelating agents (such as citric acid, etc.).3. High temperature resistance: TBHQ can be used in high temperature processed food, such as frying food, with good thermal stability.4.
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The unsaturated resin polymerization inhibitor MTBHQ (2-tert-butylhydroquinone) plays an important role in resin synthesis and other synthetic reactions. The following is a detailed analysis of its principle of action and effects:Effect Remarkable polymerization inhibition effect: MTBHQ is a kind of high efficient polymerization inhibitor for unsaturated resin. Under normal storage conditions, the general addition amount is only two ten-thousandths of the total amount of resin, and it can play a good effect of polymerization inhibition.
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T-butylhydroquinone, abbreviated as TBHQ, has a molecular formula of Cl0H1402 and a molecular weight of 166.22. [1] It is a white to light gray crystalline or crystalline powder with a very slight special odor. It is soluble in ethanol, acetic acid, ethyl ester, isopropanol, ether, and oils, and is almost insoluble in water (25 ℃,<1%; 95 ℃, 5%). TBHQ is an oil soluble antioxidant that can prevent or delay the oxidation and deterioration of fats in food.
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More than 20 countries have approved the use of TBHQ as a food antioxidant, including China, the United States, Australia, Brazil, etc. The US Food and Drug Administration (FDA) allows TBHQ to be used alone or in combination (with BHA or BHT) for oil or fatty foods, including volatile essential oils, with a maximum allowable dosage of 200PPM. It can also be used in non-alcoholic beverages, margarine, and mixed nuts.China allows TBHQ to be used as a food additive, with a maximum dosage of 0.2g/Kg.
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Tert butyl hydroquinone (TBHQ), also known as tert butyl hydroquinone, is a white crystalline powder with a melting point of 126.5-128.5 ℃ and a boiling point of 300 ℃. Its CAS number is 1948-33-0, and it is easily soluble in ethanol and ether. It is the most effective antioxidant for most oils, especially vegetable oils. T-butylhydroquinone, abbreviated as TBHQ, has a molecular formula of Cl0H1402 and a molecular weight of 166.22. [1] It is a white to light gray crystalline or crystalline powder with a very slight special odor.
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Product ParametersSynthetic grease antioxidant TBHQ, is a white or slightly reddish-brown crystalline powder with a very light special fragrance, almost insoluble in water (about 5 per cent), soluble in organic solvents such as ethanol, ethyl acetate, ether and so on.How to use the productPumping methodSeed method of preparation of TBHQ concentrated solution, through the stainless steel quantitative pump in accordance with the prescribed ratio of injection needs to be stabilized with a fixed flow rate, flow rate of fat or oil in the pipeline.
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TBHQ may volatilize faster than BHT. Therefore, the application of microcapsule technology can solve this problem under high temperature conditions. Using natural antioxidant tea polyphenols, BHA, BHT, and synergistic agent citric acid as the core material, and food grade natural substance p-cyclodextrin as the wall material, microcapsule antioxidant was prepared using microcapsule technology.Water soluble antioxidants are soluble in water and mainly used for food oxidation and discoloration.
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The pumping method injects the TBHQ concentrated solution prepared by the seed method into a pipeline with a fixed flow rate and flow rate of fat or oil that needs to be stable at a specified proportion through a stainless steel quantitative pump.It is better to mix it with 0010.02% citric acid.This product cannot be mixed with PG (Propyl Gallate) for use.
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Oil and grease antioxidant TBHQMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0TBHQ is an efficient and safe food antioxidant, which has been approved for use in more than one hundred countries and regions around the world, such as Europe, America, Asia, Australia, Africa, etc.
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When citric acid is combined with antioxidants, the higher the content of these impurities in the oil, the more obvious the synergistic effect.
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In view of the advantages of TBHQ and BHT, in recent years, BHT and TBHQ have become widely used antioxidants in fats and oil-rich foods . It should be pointed out that TBHQ and BHT have small molecular weights, are volatile and easy to sublimate, and under heating conditions, both volatilization and depletion are relatively fast, and the antioxidant performance will be generated through a series of complex redox reactions to produce the corresponding transformation products.
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It can be seen that various antioxidants have significant antioxidant effects, with the order of advantages and disadvantages being TBHQ>PG>BHA>BHT>tocopherol.And the antioxidant effect increases with the increase of the addition amount; The use of a small amount of synergist in combination with TBHQ can have a synergistic effect on antioxidant activity and enhance its antioxidant effect.Especially in areas with high room temperature, such as some southern regions of China, the sourness and flavor of instant noodles have become a hot topic of concern for instant noodle production e
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Product Parameters：Lard antioxidant TBHQ is white to light grey crystalline or crystalline powder, with very slight special smell, soluble in ethanol, acetic acid, ethyl alcohol, isopropyl alcohol, ethyl alcohol and oil, etc., a few are insoluble in water (25 ℃ <1%: 95 ℃ ﹤ 5%) TBHQ is a kind of oil-soluble antioxidant, which can prevent or prolong the oxidation of oil and fat deterioration in food.Product Applications：At present, the most commonly used antioxidants in fats and oils and their products are BHA, BHT, PG, TBHQ and tocopherol.
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The order of antioxidant activity in soybean oil is TBHQ>Vc>VE>catechins>BHT. Among them, TBHQ, VE, and BHT have good oil solubility and do not change color after heating, making them suitable for use as advanced soybean oil antioxidants. The antioxidant effect of BHT can only be displayed after a long time. Adding 20mg/kg to oil for short-term storage is better than adding 100mg/kg. Although Vc and catechins have strong antioxidant effects, they are difficult to dissolve in oil and have poor thermal stability.
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The experimental results show that adding 002% TBHQ to oil can increase the antioxidant stability of the tested oil by 2-5 times, thus extending the shelf life of oil based foods compared to adding traditional antioxidants; And the antioxidant effect increases with the increase of the addition amount; The use of a small amount of synergist in combination with TBHQ can have a synergistic effect on antioxidant activity and enhance its antioxidant effect; The antioxidant effect of TBHQ on different oils is not entirely related to the iodine value, so further research on its application and develo
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Adding citric acid has a certain synergistic effect on TBHQ antioxidant activity.
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Molecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0Palm oil antioxidant TBHQ is white to light grey crystalline or crystalline powder, with very slight special smell, soluble in ethanol, acetic acid, ethyl alcohol, isopropyl alcohol, ethyl alcohol and oil, etc., a few are insoluble in water (25 ℃ < 1%: 95 ℃ ﹤ 5%) TBHQ is a kind of oil-soluble antioxidant, which can prevent or prolong the oxidative deterioration of fats and oils in food.
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The seed method first completely dissolves TBHQ in a small amount of oil or 95% alcohol solution, and prepares 5-10% TBHQ oil or alcohol solution. Then, directly or with a measuring device, it is added to the fat or oil and stirred evenly.The pumping method injects the TBHQ concentrated solution prepared by the seed method into a pipeline with a fixed flow rate and flow rate of fat or oil that needs to be stable at a specified proportion through a stainless steel quantitative pump.
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Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0 TBHQ has been used in more than 20 countries, such as the United States, and was approved to be used in oil and fat-containing foods, fish products, biscuits, quick-cooking noodles, canned fat-containing foods, cured meat products in China in 1992.
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Product ApplicationsSuch as soybean oil, due to the presence of a large number of polyunsaturated fatty acids composed of glycerol vinegar (linoleic acid 52%, linolenic acid 8%), by the action of light, heat and air is easy to oxidative deterioration.
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Heat the oil directly to 35-60C, add TBHQ in the required proportion, vigorously stir for 10-15 minutes to dissolve it, and then continue stirring (without vigorously stirring to prevent excessive air from entering) for about 20 minutes to ensure uniform distribution of TBHQ.The seed method first completely dissolves TBHQ in a small amount of oil or 95% alcohol solution, and prepares 5-10% TBHQ oil or alcohol solution.
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