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Using isobutylene as an alkylation reagent requires a reaction under closed conditions, which can also be catalyzed by strong acids. In a mixed solvent of xylene and ketone, 85% phosphoric acid is used as a catalyst [8], and isobutylene is added to synthesize tert butylhydroquinone. The selectivity of the single tert butylation reaction can reach over 90%. Cationic resin [9] can also serve as a catalyst for this reaction, but the effect is not very ideal.
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Product Parameters：Tert-butylhydroquinone (TBHQ), also known as tert-butylhydroquinone, white crystalline powder with a point of 126.5-128.5 ℃ point of 300 ℃ CAS No.: 1948-33-0, easily soluble in alcohols and waking up to the majority of fats and oils, especially vegetable oils antioxidant function of the most effective.
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Product Parameters2-tert-butylhydroquinone as a food additive, TBHQ has been used in the United States and other more than 20 countries, China in 1992 was approved for use in oil and fat-containing foods, thousands of fish products, biscuits, quick-cooking noodles, canned fat-containing foods, cured meat products and so on.
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1.Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0As a food additive, TBHQ has been used in more than 20 countries, such as the United States, and was approved to be used in oil and fat-containing foods, fish products, biscuits, quick-cooking noodles, canned fat-containing foods, and cured meat products in China in 1992. In the United States and China, the maximum permitted dosage of TBHQ in food is 200 ppm. the effect is not very ideal. Isobutene has higher activity than tert butanol, and its application and promotion prospects are very optimistic.
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1.Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-02.Product AdvantagesIn the feed industry, there is a widely used antioxidant for ethoxyquinoline, on December 23, 2022 by the European Union formally banned, then terbutylhydroquinone, when the feed industry can completely replace the market, the market application of the forefront of very optimistic.As an antioxidant, it must meet the following requirements as much as possible: no harm to the human body; There should be no bad taste, smell, or color; Low concentration can be applied; If added to oil, it i
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2-tert-butylhydroquinone is white to light grey crystalline or crystalline powder, with very slight special smell, soluble in ethanol, acetic acid, ethyl alcohol, isopropyl alcohol, ethyl alcohol and oil, etc., a few are insoluble in water (25 ℃ <1%: 95 ℃ <5%) TBHQ is a kind of oil-soluble antioxidant, which can prevent or prolong the oxidation of the fat and oil deterioration in food.2.Product Characteristics2-Tert-butylhydroquinone is a highly efficient, low-toxic antioxidant phenolic antioxidant with excellent antioxidant effect, and the existing food antioxidants BHA, BHT, PG, etc.
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Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0Product AdvantagesNowadays, as the synthesis cost continues to decrease, the application scope is gradually expanded to petrochemical industry, feed industry, electronic industry, battery industry, etc..Academic research and developmentTertiary butylhydroquinone is a chemically synthesized antioxidant, due to its antioxidant effect, is widely used in the food industry, feed industry, petrochemical industry, paint industry, electronics industry, cosmetics industry, etc., the application prospect is very broad
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TBHQ (Tertiary Butylhydroquinone) is an oil-soluble antioxidant with excellent antioxidant properties.Broiler feed antioxidant TBHQ can prevent or delay oxidative deterioration of fats and oils in food products, and effectively prolong the shelf life of food products. Its antioxidant capacity is superior to other common antioxidants such as propyl gallate (PG), 2,6-di-tert-butyl-p-cresol (BHT) and tert-butyl-p-hydroxyanisole (BHA).
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1.Product ParametersTert-butylhydroquinone (TBHQ), also known as tert-butylhydroquinone, white crystalline powder with a point of 126.5-128.5 ℃ point of 300 ℃ CAS No.: 1948-33-0, easily soluble in alcohols and waking up to the majority of fats and oils, especially vegetable oils antioxidant function of the most effective. Tertiary butylhydroquinone (t butylhydroquinone), referred to as TBHQ molecular formula for CH1402, molecular weight of 166.22.2.Academic research and developmentLtd.
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It is soluble in ethanol, acetic acid, ethyl ester, isopropanol, ether, and oils, and is almost insoluble in water (25 ℃,<1%; 95 ℃, 5%). TBHQ is an oil soluble antioxidant that can prevent or delay the oxidation and deterioration of fats in food. As a food additive, TBHQ has been used in more than 20 countries such as the United States. In 1992, China was approved for use in oil and fat containing foods, dried fish products, biscuits, instant noodles, canned oil containing foods, pickled meat products, etc.
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With the development of farming and pet industry, the market demand for feed is increasing day by day, feed antioxidant TBHQ into the people's vision.1.Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0The experimental results show that adding 002% TBHQ to oil can increase the antioxidant stability of the tested oil by 2-5 times, thus extending the shelf life of oil based foods compared to adding traditional antioxidants; And the antioxidant effect increases with the increase of the addition amount; The use of a small amount of synergist in combination
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TBHQ or PG is also added to the baked oil to improve its stability before and during baking.Based on the actual production needs of pastries and the industry's call, our company applies to expand the scope of use of the food additive tert butylhydroquinone (TBHQ), with an application to expand the scope of use to "07.02 pastries".Therefore, appropriate selection of antioxidants can inhibit the rancidity of oily food production and prolong the storage life of the product. Shelf life is considered an effective way to prevent the product from deteriorating due to oxidation.
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1.Product CharacteristicsTertiary butylhydroquinone(TBHQ), white or slightly reddish brown crystalline powder, has a very light special fragrance, almost insoluble in water (about 5 per cent), soluble in ethanol, ethyl acetate, ether and other organic solvents.Tertiary butylhydroquinone has synergistic properties and can be used synergistically with other antioxidants (e.g. BHA, B HT) as well as chelating agents (e.g.
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Vegetable oil, animal fat, chewing gum, soup, seasoning, vitamins, grain food, nuts, essence, sausage, animal feed, grain food packaging, candy, instant potatoes, flavor substances, yeast, cosmetics, etcAs an antioxidant, it must meet the following requirements as much as possible: no harm to the human body; There should be no bad taste, smell, or color; Low concentration can be applied; If added to oil, it is fat soluble and can still maintain effective antioxidant capacity after processing; Need to be fast, effective, and cost-effectiveAntioxidants are substances that prevent or delay food o
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There are two types of antioxidants, one is chemical synthesized and the other is natural antioxidants. Chemical synthesis, such as BHT, BHQ, TBHQ, ethoxyquinoline, PE, etc., these are considered to be called chemical synthesis of antioxidants, these antioxidants have been banned in Europe, that in China and the United States, is the amount of additive per kilogram can not be greater than 0.2, these chemical synthesis of antioxidants, it is true that there is now some controversy, but the antioxidant effect is relatively good.
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Tert-butylhydroquinone, white crystalline powder its point is 126.5-128.5 ℃ point of 300 ℃ CAS No.: 1948-33-0, easily soluble in alcohols and waking up, most of the fats and oils, especially for vegetable oils antioxidant function is the most effective.
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At high temperatures, a series of complex chemical reactions such as oxidation, decomposition, polymerization, and hydrolysis are prone to occur, resulting in a rapid increase in the acid value, peroxide value, and carbon base value of roasted foods. In the later stage of storage and sales, unpleasant odors are easily produced. The use of TBHQ can effectively delay oil oxidation in pastry foods.Baked pastry foods require a higher temperature during the baking process, such as cakes and bread, which require a baking temperature of 160C~190C.
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The benefits of Feed Oil Antioxidant TBHQ are obvious. Firstly, it improves the antioxidant stability of fats and oils, making them less susceptible to oxidation during storage and processing, thus extending the shelf life of food products. Secondly, the use of Feed Oil Antioxidant TBHQ also improves the taste and flavor of food products, allowing consumers to enjoy more delicious food.
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The US Food and Drug Administration (FDA) allows TBHQ to be used alone or in combination (with BHA or BHT) for oil or fatty foods, including volatile essential oils, with a maximum allowable dosage of 200PPM. It can also be used in non-alcoholic beverages, margarine, and mixed nuts.TBHQ, also known as tert butyl hydroquinone, is a phenolic oil soluble antioxidant. TBHQ has high efficiency and stability, which can extend the shelf life of foods rich in oil and improve food safety.
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TBHQ may volatilize faster than BHT. Therefore, the application of microcapsule technology can solve this problem under high temperature conditions. Using natural antioxidant tea polyphenols, BHA, BHT, and synergistic agent citric acid as the core material, and food grade natural substance p-cyclodextrin as the wall material, microcapsule antioxidant was prepared using microcapsule technology.Water soluble antioxidants are soluble in water and mainly used for food oxidation and discoloration.
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1.Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-02-Tertiary butyl dihydroquinone, also known as tert-butylhydroquinone, white crystalline powder with a point of 126.5-128.5 ℃ point of 300 ℃ CAS No.: 1948-33-0, easily soluble in alcohols and waking up to the majority of fats and oils, especially vegetable oils antioxidant function of the most effective.
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Scope of applicationAccording to GB2760(0.4007), the hygienic standard of the People's Republic of China for the use of food additives, TBHQ can be used in edible fats and oils, deep-fried food, dried fish products, biscuits, instant noodle, instant rice, canned dried fruits, cured meat products, roasted and stir-fried nuts (February 2007 supplement), etc. The maximum use level is 0.2g/kg, and the general recommended use level is 0.01~0.02% of the total amount of fats and oils.
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Introduction of nature:TBHQ is sort of insoluble in water (approximately five‰), soluble in ethanol, acetic acid, ethanol, isopropyl alcohol, ether and vegetable oil, lard, and so forth. Nearly insoluble in water (25℃, <1%). Boiling factor 295℃, melting factor 126 -128.5℃. It has the effect of stopping the failure of most fats and oils, specially vegetable oils. It does no longer trade color in touch with iron and copper, but can turn red if alkali is present.
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Product ParametersTert-butylhydroquinone (TBHQ), also known as tert-butylhydroquinone, white crystalline powder with a point of 126.5-128.5 ℃ point of 300 ℃ CAS No.: 1948-33-0, easily soluble in alcohols and waking up to the majority of fats and oils, especially vegetable oils antioxidant function of the most effective.
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